A case study on fuel oil contamination in a mangrove swamp in Hong Kong   总被引：5，自引：0，他引：5  

Tam NF  Wong TW  Wong YS 《Marine pollution bulletin》2005,51(8-12):1092-1100

Mangroves commonly found along tropical and subtropical coastlines are susceptible to oil pollution. In December 2000, around 500 1 m tall Kandelia candel saplings at the age of 3–5 years old located at the foreshore region of Sheung Pak Nai swamp, Hong Kong SAR, were found to be damaged by oil pollution. More than 80% of the saplings were either dead or washed away and leaving less than 5% healthy saplings with dense green leaves. Elevated concentrations of light n-alkanes (ranging from n-C₁₄ to n-C₂₀), pristane and phytane were recorded in surface sediments collected in December 2000. The ratio between light and total n-alkanes was 0.4. The total petroleum hydrocarbons (60–80 μg g⁻¹ TPH) and unresolved complex mixtures (60–70 μg g⁻¹ UCM) were higher than the background values of other mangrove sediments in Hong Kong, which were 40 and 20 μg g⁻¹, respectively. In certain root zone sediments, TPH concentrations were above 1000 μg g⁻¹. These results suggest that surface sediments in Sheung Pak Nai were contaminated by petroleum oil, most likely by illegal discharge of fuel oil which occurred between 1998 and 2002. One year later, in December 2001, unhealthy saplings had recovered and re-grown. The concentrations of TPH and UCM in sediments declined to around 40 μg g⁻¹, pristane and phytane dropped by 80%, and the ratio of light to total n-alkanes was 0.15, suggesting that residual oil in sediments was weathered leading to a remarkable recovery of the unhealthy saplings.  相似文献   

Drying of salt-contaminated masonry: MRI laboratory monitoring     

Teresa Diaz Gonçalves  Leo Pel  José Delgado Rodrigues 《Environmental Geology》2007,52(2):293-302

Drying of masonry specimens was monitored by means of a two-dimensional (2D) magnetic resonance imaging (MRI) technique. The external surfaces stayed wet for longer if NaCl was present instead of pure water only. This corroborates many practical observations that salts aggravate dampness in masonry. A slower evaporation process and not hygroscopicity was the cause. That suggests that salt-induced dampness may, in general, arise simply from changes in the drying process of masonry materials. That also implies that the height and depth at which crystallization occurs in walls may depend on the relative equilibrium humidity (RHeq) and other properties of salts that influence drying of porous materials. Evaporation rates of free surfaces of pure water and saturated NaCl solution were measured by a gravimetric technique. The results indicate that slow drying of salt-contaminated materials is not due only to the lower RHeq of salt solutions. The effective surface of evaporation is likely to be reduced perhaps due to blocking of pores by salt crystals. Final salt-distribution maps of the specimens show that: (a) salts may affect the inner materials of the masonry, even in evaporation-induced processes that lead crystallization to occur predominantly on the external surface; (b) distinct internal distribution patterns occur if masonry composition varies. Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.  相似文献   

Rapid characterisation of the extremely large landslide threatening the Rules Reservoir (Southern Spain)     

Reyes-Carmona  Cristina  Galve  Jorge Pedro  Moreno-Sánchez  Marcos  Riquelme  Adrián  Ruano  Patricia  Millares  Agustín  Teixidó  Teresa  Sarro  Roberto  Pérez-Peña  José Vicente  Barra  Anna  Ezquerro  Pablo  López-Vinielles  Juan  Béjar-Pizarro  Marta  Azañón  José Miguel  Monserrat  Oriol  Mateos  Rosa María 《Landslides》2021,18(12):3781-3798

Landslides - When an active landslide is first identified in an artificial reservoir, a comprehensive study has to be quickly conducted to analyse the possible hazard that it may represent to such...  相似文献   

Multi-stage Ag–Bi–Co–Ni–U and Cu–Bi vein mineralization at Wittichen,Schwarzwald, SW Germany: geological setting,ore mineralogy,and fluid evolution     

Sebastian?Staude  Wolfgang?Werner  Teresa?Mordhorst  Klaus?Wemmer  Dorrit?E.?Jacob  Gregor?MarklEmail author 《Mineralium Deposita》2012,47(3):251-276

The Wittichen Co–Ag–Bi–U mining area (Schwarzwald ore district, SW Germany) hosts several unconformity-related vein-type mineralizations within Variscan leucogranite and Permian to Triassic redbeds. The multistage mineralization formed at the intersection of two fault systems in the last 250 Ma. A Permo-Triassic ore stage I with minor U–Bi–quartz–fluorite mineralization is followed by a Jurassic to Cretaceous ore stage II with the main Ag and Co mineralization consisting of several generations of gangue minerals that host the sub-stages of U–Bi, Bi–Ag, Ni–As–Bi and Co–As–Bi. Important ore minerals are native elements, Co and Ni arsenides, and pitchblende; sulphides are absent. The Miocene ore stage III comprises barite with the Cu–Bi sulfosalts emplectite, wittichenite and aikinite, and the sulphides anilite and djurleite besides native Bi, chalcopyrite, sphalerite, galena and tennantite. The mineral-forming fluid system changed from low salinity (<5 wt.% NaCl) at high temperature (around 300°C) in Permian to highly saline (around 25 wt.% NaCl + CaCl₂) at lower temperatures (50–150°C) in Triassic to Cretaceous times. Thermodynamic calculations and comparison with similar mineralizations worldwide show that the Mesozoic ore-forming fluid was alkaline with redox conditions above the hematite–magnetite buffer. We suggest that the precipitation mechanism for native elements, pitchblende and arsenides is a decrease in pH during fluid mixing processes. REE patterns in fluorite and the occurrence of Bi in all stages suggest a granitic source of some ore-forming elements, whereas, e.g. Ag, Co and Ni probably have been leached from the redbeds. The greater importance of Cu and isotope data indicates that the Miocene ore stage III is more influenced by fluids from the overlying redbeds and limestones than the earlier mineralization stages.  相似文献   

Badland susceptibility assessment in Volterra municipality (Tuscany,Italy) by means of GIS and statistical analysis     

Silvia Bianchini  Matteo Del Soldato  Lorenzo Solari  Teresa Nolesini  Fabio Pratesi  Sandro Moretti 《Environmental Earth Sciences》2016,75(10):889

  相似文献   

Geochronology of a composite granitoid pluton: a high-precision ID-TIMS U–Pb zircon study of the Variscan Karkonosze Granite (SW Poland)     

Ryszard Kryza  Urs Schaltegger  Teresa Oberc-Dziedzic  Christian Pin  Maria Ovtcharova 《International Journal of Earth Sciences》2014,103(3):683-696

Resolving time differences between successive magmatic pulses in composite granitoid plutons is often a difficult task. High-precision CA-ID-TIMS zircon ages obtained from such a pluton, the Variscan Karkonosze Granite (NE part of the Bohemian Massif), provide evidence that the crystallization of the two main granite facies, porphyritic and equigranular, happened between 312.5 ± 0.3 and 312.2 ± 0.3 Ma, thus unresolvable at the 0.08–0.1 % precision level of a single ²⁰⁶Pb/²³⁸U age. This finding is at odds with most other previous dating attempts and asks for a re-evaluation of the previous scattered geochronological data. The main reasons for the scatter of the earlier dates obtained by various techniques can include analytical causes, the presence of older inheritance and disturbance of the U–Pb isotopic system, due to zircon metamictization (enhanced by high-U content in zircon) or late- and post-magmatic alteration.  相似文献   

Asbestos and other fibrous minerals contained in the serpentinites of the Gimigliano-Mount Reventino Unit (Calabria,S-Italy)   总被引：1，自引：1，他引：0  

Andrea Bloise  Teresa Critelli  Manuela Catalano  Carmine Apollaro  Domenico Miriello  Alessandro Croce  Eugenio Barrese  Francesca Liberi  Eugenio Piluso  Caterina Rinaudo  Elena Belluso 《Environmental Earth Sciences》2014,71(8):3773-3786

Serpentinites are metamorphic rocks with good technological properties and valuable ornamental characteristics, which have been exploited since ancient times. Actually, their use is limited and monitored in several countries worldwide because they can contain fibrous asbestos minerals that may be carcinogenic. Furthermore, certain types of fibrous minerals can be confused with asbestos, and must therefore be carefully investigated. We have investigated the possible presence of the asbestos and non-asbestos fibrous phases contained in serpentinitic rocks in a meta-ophiolitic sequence from the Gimigliano-Mount Reventino Unit (Southern Italy), which had not been previously assessed. The detection and quantification of asbestos and the correct distinction of the fibrous non-asbestos minerals are very important not only from a scientific point of view, but also from a legislative one. This is especially the case for the administrative agencies that have to take decisions with regards to the implementation of public and occupational health protection measures (e.g., in road yards and quarry excavations). As a consequence of this, serpentinitic rock samples have been characterized in detail through X-ray powder diffraction, scanning and transmission electron microscopy combined with energy-dispersive spectrometry, analytical electron microscopy (SEM–EDS and TEM–AEM), differential scanning calorimetry, thermogravimetry and micro-Raman spectroscopy. Two kinds of asbestos and four kinds of non-asbestos fibrous silicates have been detected in the examined samples. In order of decreasing abundance these are polygonal serpentine, chrysotile, fibrous antigorite, tremolite, gedrite and magnesiohornblende. The size, morphology, crystallinity and chemical composition of the fibres were also discussed, in the light of the possible role these properties could play in the carcinogenic effect on human health.  相似文献   

Alteration kinetics of natural stones due to sodium sulfate crystallization: can reality match experimental simulations?     

Teresa Diaz Gonçalves  Vânia Brito 《Environmental Earth Sciences》2014,72(6):1789-1799

Salt decay is a very destructive mechanism that affects frequently the porous building materials of our architectural heritage. Sodium sulfate is one of the salts found in this context. It usually demonstrates high destructive power in salt crystallization tests because it can crystallize not only during evaporative processes but also when the temperature drops or when the salt solution comes into contact with pre-existing crystals. However, the use of extreme temperatures or successive wet/dry cycles also makes these tests unrepresentative of reality. To verify whether sodium sulfate can also be so destructive in field conditions, we have performed crystallization tests consisting of a single isothermal drying event. Three natural stones, relevant for the architectural heritage, were used for the purpose: Bentheimer sandstone, Ançã limestone, and a current Portuguese limestone of low porosity. The stones gave rise to distinct salt decay patterns: efflorescence, multilayer delamination and unilayer delamination, respectively. These morphological alterations were characterized at the micrometer scale by a new method based on what we have called the alteration kinetics curve. Such curve is calculated from topographic profiles obtained by a non-contact optical technique. The multilayer and unilayer delamination decay were also monitored by time-lapse photography. The work led us to conclude that sodium sulfate can indeed be also very destructive in field-representative conditions. Moreover, it showed that the optical method can be a valuable aid in the development of more realistic salt crystallization tests.  相似文献   

Sublimation Mechanisms of Comet Nuclei     

Capria  Maria Teresa 《Earth, Moon, and Planets》2000,89(1-4):161-178

In this paper the sublimation mechanisms of parent molecules from nuclei will be reviewed from the point of view of theoretical models, and the results of models will be compared with the results of the extensive observation campaign of C/1995 O1 Hale-Bopp. The simple model of a mixture of ices in which each gas sublimates independently from the others when the right temperature has been reached is in many cases inadequate to explain the observations. Many minor volatiles can be trapped in the amorphous water ice and released in a complex way when particular ranges of temperature are reached. The presence of sublimating icy grains in the inner coma of comets, suggested many years ago, seems now to be proven, at least for Hale-Bopp. From these grains a significant amount of water and other volatiles could contribute to the total flux measured in the coma. The unprecedented coverage of Hale-Bopp’s gas production curve for such a long time and with so many instrumentshas offered to modellers a wonderful occasion to test and compare observation results with the predictions of sublimation models, demonstrating that current models are able to explain observed results.  相似文献   

Reappraisal of the GL‐O Reference Material for K‐Ar Dating: New Insight from Microanalysis,Single‐Grain and Milligram Ar Measurements     

Thomas Boulesteix  Jesús Sol  Teresa Pi  Michel Cathelineau 《Geostandards and Geoanalytical Research》2020,44(2):287-306

The homogeneity and Ar‐dating suitability of the GL‐O reference material were re‐evaluated to determine whether this material is sufficiently homogeneous to be suitable for the calibration of modern high sensitivity instruments. Based on new micro‐analyses and noble gas determinations, our contribution reveals several kinds of inhomogeneity at the grain scale: disparity in the glauconitisation among and within the pellets, variable occurrence of a phosphatic component within pellets (1% m/m on average), and rare occurrences of calcite and detrital grains. Measurements on test portions of ≤ 1 mg reflect such heterogeneity with variability in ⁴⁰Ar* content that exceeds analytical uncertainty, including a few highly anomalous values. The lesser evolved glauconite population yielded ⁴⁰Ar* contents ~ 15% lower than the value of 24.8 nl g^?1 recommended by Odin et al. (1982, Numerical dating in stratigraphy. Wiley (Chichester, UK), 123–148). But the measured concentrations of ⁴⁰Ar* converge towards the aforementioned value as test portion mass increased to > 3 mg. A few rare 3 mg experiments still yielded ⁴⁰Ar* contents lower than the recommended value (down to 24.0 nl g^?1), and we recommend using more conservative minimum masses of 5–10 mg. A further purification step for GL‐O or the intercalibration of its powder version could be considered to diminish the size of the test portions and the intensity of the measured signals.  相似文献